Safety Data Sheet according to (EC) No 1907/2006

Page 1 of 12
SDS No. : 152852
V004.0
LOCTITE SI 5699 GY known as 5699 GREY 300ML DE FR GB Revision: 11.11.2015
NL printing date: 01.08.2016
Replaces version from: 18.03.2015

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
LOCTITE SI 5699 GY known as 5699 GREY 300ML DE FR GB NL

Contains:
Silicon compounds
Butanone oxime
Butan-2-one O,O',O'',O'''-silanetetrayltetraoxime

1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use:
Silicone sealant

1.3. Details of the supplier of the safety data sheet

Henkel Ltd
Wood Lane End
HP2 4RQ Hemel Hempstead

Great Britain

Phone: +44 1442 278000

Fax-no.: +44 1442 278071

[email protected]

1.4. Emergency telephone number

24 Hours Emergency Tel: +44 (0)1442 278497

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (CLP):
Serious eye damage Category 1
H318 Causes serious eye damage.
Skin sensitizer Category 1
H317 May cause an allergic skin reaction.
Carcinogenicity Category 2
H351 Suspected of causing cancer.

2.2. Label elements

Label elements (CLP):

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Hazard pictogram:

Signal word: Danger

Hazard statement: H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.
H351 Suspected of causing cancer.

Precautionary statement: P280 Wear protective gloves/protective clothing/eye protection/face protection.

Prevention

Precautionary statement: P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
Response contact lenses, if present and easy to do. Continue rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

2.3. Other hazards

Methyl ethyl ketoxime is formed during cure.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

General chemical description:

Silicone sealant

Declaration of the ingredients according to CLP (EC) No 1272/2008:

Hazardous components EC Number content Classification

CAS-No. REACH-Reg No.
Silicon compounds 5- < 10 % Skin Sens. 1
H317
Eye Dam. 1
H318
STOT RE 2
H373
Butanone oxime 202-496-6 1- < 5 % Carc. 2
96-29-7 01-2119539477-28 H351
Eye Dam. 1
H318
Skin Sens. 1
H317
Acute Tox. 4; Dermal
H312
Flam. Liq. 3
H226
Butan-2-one O,O',O'',O'''- 251-882-0 0,1- < 1 % Flam. Sol. 1
silanetetrayltetraoxime 01-2119982966-14 H228
34206-40-1 Skin Sens. 1
H317
Eye Irrit. 2
H319
STOT RE 2
H373

For full text of the H - statements and other abbreviations see section 16 "Other information".
Substances without classification may have community workplace exposure limits available.

Methyl ethyl ketoxime is formed during cure.

SECTION 4: First aid measures
4.1. Description of first aid measures
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Inhalation:
Move to fresh air. If symptoms persist, seek medical advice.

Skin contact:
Rinse with running water and soap.
Obtain medical attention if irritation persists.

Eye contact:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Seek medical advice.

Ingestion:
Do not induce vomiting.
Seek medical advice.

4.2. Most important symptoms and effects, both acute and delayed
EYE: Irritation, conjunctivitis.

SKIN: Rash, Urticaria.

4.3. Indication of any immediate medical attention and special treatment needed
See section: Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media:
Carbon dioxide, foam, powder

Extinguishing media which must not be used for safety reasons:

None known

5.2. Special hazards arising from the substance or mixture

Do not expose to direct heat.
5.3. Advice for firefighters
Wear self-contained breathing apparatus.

Additional information:
In case of fire, keep containers cool with water spray.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Avoid contact with skin and eyes.

6.2. Environmental precautions

Do not let product enter drains.

6.3. Methods and material for containment and cleaning up

Scrape up as much material as possible.
Ensure adequate ventilation.
Store in a partly filled, closed container until disposal.

6.4. Reference to other sections

See advice in section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Use only in well-ventilated areas.
Vapours should be extracted to avoid inhalation.
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Hygiene measures:
Good industrial hygiene practices should be observed.
Wash hands before work breaks and after finishing work.
Do not eat, drink or smoke while working.

7.2. Conditions for safe storage, including any incompatibilities

Store in a cool, well-ventilated place.
Never allow product to get in contact with water during storage

7.3. Specific end use(s)

Silicone sealant

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational Exposure Limits

Valid for
Great Britain

Ingredient [Regulated substance] ppm mg/m3 Value type Short term exposure limit Regulatory list
category / Remarks
Calcium carbonate 10 Time Weighted Average EH40 WEL
471-34-1 (TWA):
[CALCIUM CARBONATE, INHALABLE
DUST]
Calcium carbonate 4 Time Weighted Average EH40 WEL
471-34-1 (TWA):
[CALCIUM CARBONATE, RESPIRABLE
DUST]
Calcium carbonate 4 Time Weighted Average EH40 WEL
471-34-1 (TWA):
[LIMESTONE, RESPIRABLE
MARBLE, RESPIRABLE]
Calcium carbonate 10 Time Weighted Average EH40 WEL
471-34-1 (TWA):
[LIMESTONE, TOTAL INHALABLE
MARBLE, TOTAL INHALABLE]

Occupational Exposure Limits

Valid for
Ireland

Ingredient [Regulated substance] ppm mg/m3 Value type Short term exposure limit Regulatory list
category / Remarks
Calcium carbonate 4 Time Weighted Average IR_OEL
471-34-1 (TWA):
[CALCIUM CARBONATE, RESPIRABLE
DUST]
Calcium carbonate 10 Time Weighted Average IR_OEL
471-34-1 (TWA):
[CALCIUM CARBONATE, TOTAL
INHALABLE DUST]
Butanone oxime 3 10 Time Weighted Average IR_OEL
96-29-7 (TWA):
[METHYL ETHYL KETOXIME]
Butanone oxime 10 33 Short Term Exposure IR_OEL
96-29-7 Limit (STEL):
[METHYL ETHYL KETOXIME]

Biological Exposure Indices:

None

8.2. Exposure controls:

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Respiratory protection:
Ensure adequate ventilation.
An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly
ventilated area
Filter type: A (EN 14387)

Hand protection:
Chemical-resistant protective gloves (EN 374).
Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes
permeation time as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time
as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy
with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably
shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g.
temperature). If signs of wear and tear are noticed then the gloves should be replaced.

Eye protection:
Wear protective glasses.
Protective eye equipment should conform to EN166.

Skin protection:
Wear suitable protective clothing.
Protective clothing should conform to EN 14605 for liquid splashes or to EN 13982 for dusts.

Advices to personal protection equipment:

The information provided on personal protective equipment is for guidance purposes only. A full risk assessment should be
conducted prior to using this product to determine the appropriate personal protective equipment to suit local conditions.
Personal protective equipment should conform to the relevant EN standard.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance paste
grey
Odor odorless
Odour threshold No data available / Not applicable

pH Not applicable
pH Not applicable
Initial boiling point > 200 °C (> 392 °F)
Flash point > 93 °C (> 199.4 °F)
Decomposition temperature No data available / Not applicable
Vapour pressure < 5 mm hg
(50 °C (122 °F))
Vapour pressure < 700 mbar
(50 °C (122 °F))
Density 1,5 g/cm3
(20 °C (68 °F))
Bulk density No data available / Not applicable
Viscosity No data available / Not applicable
Viscosity (kinematic) No data available / Not applicable
Explosive properties No data available / Not applicable
Solubility (qualitative) Polymerises in presence of water.
(Solvent: Water)
Solidification temperature No data available / Not applicable
Melting point Not available.
Flammability No data available / Not applicable
Auto-ignition temperature No data available / Not applicable
Explosive limits No data available / Not applicable
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Partition coefficient: n-octanol/water No data available / Not applicable

Evaporation rate No data available / Not applicable
Vapor density No data available / Not applicable
Oxidising properties No data available / Not applicable

9.2. Other information

No data available / Not applicable

SECTION 10: Stability and reactivity

10.1. Reactivity
Polymerises in presence of water.

10.2. Chemical stability

Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

See section reactivity

10.4. Conditions to avoid

Stable
Exposure to air or moisture over prolonged periods.

10.5. Incompatible materials

None if used properly.

10.6. Hazardous decomposition products

Methyl ethyl ketoxime formed during cure.
Methanol is liberated slowly upon exposure to moisture.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

General toxicological information:

The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for
mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological
information for the substances listed under Section 3 is provided in the following.

Oral toxicity:
May cause irritation to the digestive tract.
Ingestion of large quantities may cause liver or kidney damage.

Inhalative toxicity:
Methylethyl ketoxime released during polymerisation of oxime curing RTV silicones is irritating to the respiratory system

Skin irritation:
Methylethyl ketoxime released during polymerisation of oxime curing silicones. It is harmful in contact with skin and is a skin
sensitizer.

Eye irritation:
Causes serious eye damage.

Sensitizing:
May cause an allergic skin reaction.
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Carcinogenicity:
Suspected of causing cancer

Acute oral toxicity:

Hazardous components Value Value Route of Exposure Species Method

CAS-No. type application time
Silicon compounds LD50 > 2.000 mg/kg oral rat OECD Guideline 401 (Acute
Oral Toxicity)
Butanone oxime LD50 2.326 mg/kg oral rat OECD Guideline 401 (Acute
96-29-7 Oral Toxicity)
Butan-2-one O,O',O'',O'''- LD50 2.463 mg/kg oral rat OECD Guideline 401 (Acute
silanetetrayltetraoxime Oral Toxicity)
34206-40-1

Acute inhalative toxicity:

Hazardous components Value Value Route of Exposure Species Method

CAS-No. type application time

Acute dermal toxicity:

Hazardous components Value Value Route of Exposure Species Method

CAS-No. type application time
Silicon compounds LD50 > 2.000 mg/kg dermal rat OECD Guideline 402 (Acute
Dermal Toxicity)
Butanone oxime Acute 1.100 mg/kg dermal Expert judgement
96-29-7 toxicity
estimate
(ATE)
Butanone oxime LD50 > 1.000 mg/kg rabbit OECD Guideline 402 (Acute
96-29-7 Dermal Toxicity)
Butan-2-one O,O',O'',O'''- LD50 > 2.000 mg/kg dermal rat OECD Guideline 402 (Acute
silanetetrayltetraoxime Dermal Toxicity)
34206-40-1

Serious eye damage/irritation:

Hazardous components Result Exposure Species Method

CAS-No. time
Butanone oxime Category 1 (irreversible effects on the eye) rabbit OECD Guideline 405 (Acute
96-29-7 Eye Irritation / Corrosion)
Butan-2-one O,O',O'',O'''- irritating 1h rabbit OECD Guideline 405 (Acute
silanetetrayltetraoxime Eye Irritation / Corrosion)
34206-40-1

Respiratory or skin sensitization:

Hazardous components Result Test type Species Method

CAS-No.
Silicon compounds sensitising Guinea pig guinea pig OECD Guideline 406 (Skin
maximisat Sensitisation)
ion test
Butanone oxime sensitising Guinea pig guinea pig OECD Guideline 406 (Skin
96-29-7 maximisat Sensitisation)
ion test
Butan-2-one O,O',O'',O'''- sensitising Guinea pig guinea pig OECD Guideline 406 (Skin
silanetetrayltetraoxime maximisat Sensitisation)
34206-40-1 ion test

Germ cell mutagenicity:

Hazardous components Result Type of study / Metabolic Species Method

CAS-No. Route of activation /
administration Exposure time
Silicon compounds negative bacterial reverse with and without OECD Guideline 471
mutation assay (e.g (Bacterial Reverse Mutation
Ames test) Assay)
Silicon compounds negative intraperitoneal mouse OECD Guideline 474
(Mammalian Erythrocyte
Micronucleus Test)
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Repeated dose toxicity

Hazardous components Result Route of Exposure time / Species Method

CAS-No. application Frequency of
treatment
Silicon compounds NOAEL=10 mg/kg oral: gavage rat OECD Guideline 422
(Combined Repeated Dose
Toxicity Study with the
Reproduction / Developmental
Toxicity Screening Test)
Butan-2-one O,O',O'',O'''- NOAEL=25 mg/kg oral: 90 ddaily: ad libitum rat OECD Guideline 408
silanetetrayltetraoxime drinking (Repeated Dose 90-Day Oral
34206-40-1 water Toxicity in Rodents)

SECTION 12: Ecological information

General ecological information:
The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for
mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological
information for the substances listed under Section 3 is provided in the following.
Cured Loctite products are typical polymers and do not pose any immediate environmental hazards.
Precautions required with respect to Environmental Hazards of articles in which this product is used should be considered.

12.1. Toxicity

Ecotoxicity:
Do not empty into drains / surface water / ground water.
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Hazardous components Value Value Acute Exposure Species Method

CAS-No. type Toxicity time
Study
Butanone oxime LC50 320 - 1.000 mg/l Fish 96 h Leuciscus idus DIN 38412-15
96-29-7
NOEC 50 mg/l Fish 14 d Oryzias latipes OECD Guideline
204 (Fish,
Prolonged Toxicity
Test: 14-day Study)
Butanone oxime EC50 > 500 mg/l Daphnia 48 h Daphnia magna EU Method C.2
96-29-7 (Acute Toxicity for
Daphnia)
Butanone oxime EC50 11,8 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline
96-29-7 201 (Alga, Growth
Inhibition Test)
NOEC 2,56 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline
201 (Alga, Growth
Inhibition Test)
Butanone oxime EC10 177 mg/l Bacteria 17 h DIN 38412, part 8
96-29-7 (Pseudomonas
Zellvermehrungshe
mm-Test)
Butanone oxime NOEC > 100 mg/l chronic 21 d Daphnia magna OECD 211
96-29-7 Daphnia (Daphnia magna,
Reproduction Test)
Butan-2-one O,O',O'',O'''- LC50 843 mg/l Fish 96 h Pimephales promelas OECD Guideline
silanetetrayltetraoxime 203 (Fish, Acute
34206-40-1 Toxicity Test)
NOEC 50 mg/l Fish 14 d Oryzias latipes OECD Guideline
204 (Fish,
Prolonged Toxicity
Test: 14-day Study)
Butan-2-one O,O',O'',O'''- EC50 201 mg/l Daphnia 48 h Daphnia magna OECD Guideline
silanetetrayltetraoxime 202 (Daphnia sp.
34206-40-1 Acute
Immobilisation
Test)
Butan-2-one O,O',O'',O'''- EC50 16 mg/l Algae 72 h Selenastrum capricornutum OECD Guideline
silanetetrayltetraoxime (new name: Pseudokirchnerella 201 (Alga, Growth
34206-40-1 subcapitata) Inhibition Test)
NOEC 2,6 mg/l Algae 72 h Selenastrum capricornutum OECD Guideline
(new name: Pseudokirchnerella 201 (Alga, Growth
subcapitata) Inhibition Test)
Butan-2-one O,O',O'',O'''- NOEC > 100 mg/l chronic 21 d Daphnia magna OECD 211
silanetetrayltetraoxime Daphnia (Daphnia magna,
34206-40-1 Reproduction Test)

12.2. Persistence and degradability

Persistence and Biodegradability:

The product is not biodegradable.

Hazardous components Result Route of Degradability Method

CAS-No. application
Butanone oxime inherently biodegradable aerobic 70 % OECD Guideline 302 B (Inherent
96-29-7 biodegradability: Zahn-
Wellens/EMPA Test)
Butan-2-one O,O',O'',O'''- Not readily aerobic 28 % OECD Guideline 301 C (Ready
silanetetrayltetraoxime biodegradable. Biodegradability: Modified MITI
34206-40-1 Test (I))

12.3. Bioaccumulative potential / 12.4. Mobility in soil

Mobility:
Cured adhesives are immobile.

Bioaccumulative potential:
Does not bioaccumulate.

Hazardous components LogKow Bioconcentration Exposure Species Temperature Method

CAS-No. factor (BCF) time
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Butanone oxime 0,5 - 0,6 42 d Oryzias latipes 25 °C OECD Guideline 305 C

96-29-7 (Bioaccumulation: Test for
the Degree of
Bioconcentration in Fish)
Butanone oxime 0,65 25 °C OECD Guideline 107
96-29-7 (Partition Coefficient (n-
octanol / water), Shake
Flask Method)

12.5. Results of PBT and vPvB assessment

No data available.

12.6. Other adverse effects

No data available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product disposal:
Dispose of in accordance with local and national regulations.
Contribution of this product to waste is very insignificant in comparison to article in which it is used

Disposal of uncleaned packages:

After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an
authorised legal land fill site or incinerated.
Disposal must be made according to official regulations.

Waste code
08 04 09 waste adhesives and sealants containing organic solvents and other dangerous substances

SECTION 14: Transport information

14.1. UN number

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.2. UN proper shipping name

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.3. Transport hazard class(es)

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.4. Packing group

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.5. Environmental hazards

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.6. Special precautions for user

Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not applicable
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SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
VOC content <5%
(2010/75/EC)

15.2. Chemical safety assessment

A chemical safety assessment has not been carried out.

SECTION 16: Other information

The labelling of the product is indicated in Section 2. The full text
of all abbreviations indicated by codes in this safety data sheet are as follows:
H226 Flammable liquid and vapor.
H228 Flammable solid.
H312 Harmful in contact with skin.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.

Further information:
This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular
properties.

Label elements (DPD):

Xn - Harmful

Risk phrases:
R36 Irritating to eyes.
R40 Limited evidence of a carcinogenic effect.
R43 May cause sensitisation by skin contact.

Safety phrases:
S22 Do not breathe dust.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 Wear suitable protective clothing and gloves.
S60 This material and its container must be disposed of as hazardous waste.

Contains:
Silicon compounds,
Butanone oxime

Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document.
Corresponding text is displayed in a different color on shadowed fields.
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