10-08-2025

9610ZJA801896250007 JA

PART 1 : PHYSICS

SECTION-I (i)

1) A small bead of mass m can move on a smooth circular wire (radius R) under the action of a force

directed (r = position of bead from P & K = constant) towards a point P within the circle at

a distance from the centre. What should be the minimum velocity of bead at the point of the wire

nearest the centre of force (P) so that bead will complete the circle?

(A)

(B)

(C)

(D) None of these

2) A wedge of mass M fitted with a spring of stiffness 'k' is kept on a smooth horizontal surface. A
rod of mass m is kept on the wedge as shown in the figure. System is in equilibrium. Assuming that

all surfaces are smooth, the potential energy stored in the spring is:

(A)

(B)
(C)

(D)

3) A ring of mass m = 30g slides over a smooth vertical rod. Attached to the ring is a light string
passing over a smooth fixed pulley at a distance of 0.8 m from the rod. At the other end of the string,
there is a mass M = 50 g. The ring is held level with the pulley and then released (see figure).
Determine the distance by which the mass m moves down before coming to rest for the first time.

(A) 1.5m
(B) 0.75m
(C) 5m
(D) 2.5m

4) These questions consist of two statements each, printed as Assertion and Reason.
While answering these Questions you are required to choose any one of the following four
responses.
Assertion : No work is done by a force on a object when the point of application of the force does
not move.
Reason : A small block of mass m is kept on a rough inclined surface of inclination α fixed in an
elevator. The elevator goes up with a uniform velocity u and the block does not slide on the wedge.
Then the work done by the force of friction on the block in time t will be mg ut sin2 α.

(A) If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.
(B) If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.
(C) If Assertion is True but the Reason is False.
(D) If both Assertion & Reason are false.

SECTION-I (ii)

1) A single conservative force F(x) acts on a particle that moves along the x-axis. The graph of the
potential energy with x is given. At x = 5m, the particle has a kinetic energy of 50J and its potential
energy is related to position ‘x’ as U = 15 + (x – 3)2 Joule, where x is in meter. Then:
(A) The mechanical energy of system is 69 J.
(B) The mechanical energy of system is 19J.
(C) At x = 3, the kinetic energy of particle is minimum.
(D) The maximum value of kinetic energy is 54 J.

2) A cylinder of radius R is fixed on a smooth horizontal table with a mass m attached to its
circumference by a string of length as shown in figure. If mass is given a tangential velocity v at t
= 0 and it strikes the cylinder at point P at time t then for motion upto P.

(A)
Time after which the mass hits the cylinder is

(B)
Total distance travelled by the mass is
(C) The minimum value of v for which the mass will hit the cylinder is zero

(D)
Change in kinetic energy is

3) A massless bucket is initially at rest next to one end of a chain that lies in a straight line on the
floor, as shown in Fig. The chain has uniform mass density (kg/m). You push on the bucket (so that
it gathers up the chain) with the force F(t) that gives the bucket and whatever chain is inside, a
constant acceleration a at all times. 't' is time. There is no friction between the bucket and the floor.

(A)
F(t) at time t is

(B)
work done by F(t) upto time t is
(C)
F(t) at time t is

(D)
work done by F(t) upto time t is

SECTION-II

1) A circular tube of mass M is placed vertically on a horizontal surface as shown in the figure. Two
small spheres, each of mass m, just fit in the tube, are released from the top. If θ gives the angle
between radius vector of either ball with the vertical, obtain the value of the ratio M/m if the tube

breaks its contact with ground when θ = 60°. Neglect any friction.

2) A particle of mass m = 5 kg is free to slide on a smooth ring of radius r = 20 cm fixed in a vertical

plane. The particle attached to one end of a spring whose other end is fixed to the top point O of the
ring. Initially the particle is at rest at a point A of the ring such that ∠OCA = 60º, C being the centre
of the ring. The natural length of the spring is also equal to r = 20 cm. After the particle is released
it slides down the ring. The contact force between the particle and the ring becomes zero when it
reaches the lowest position B (diametrically opposite to O). Determine the force constant (in N/m) of

the spring.

3) A prototype train of length l = 168 m is running at a constant speed v with its engine off on
horizontal portion of a track that has a hilly portion as shown in the figure. Dimensions of the hilly
portion are a = 60 m, b = 80 m and c = 100 m respectively.

What should the minimum speed of the train

be to pass over the hill?
For simplicity, assume size of a bogie negligible as compared to the rounded portions of the hill and
size of the rounded portions as compared to the straight portions. All kinds of resistive and
frictional forces are absent. Use acceleration of free fall g = 10 m/s2.

4) Figure shows a frictionless circular path lying in vertical plane. The path consist of two
semicircular path ACB and ADB. One end of the spring is fixed to the block and other and other end
is fixed at centre O. Natural length of the spring is 2R (where R is the radius of circle), whereas its

spring constant is (m is the mass of the particle. The block is given velocity at the
bottom and it reaches at the top point. At this position part ACB is suddenly removed (vertically
upward). Let a1, a2 be the magnitude accelerations of the block just before and just after removal of

ACB then the value of .

5) A horizontal frictionless thin light rod wear a sleeve of mass = 0.25 kg is being rotated with
constant speed ω = 2 rad/s about a vertical axis passing through its one end as shown in figure.
Initially the sleeve is at a distance r = r1 from the axis. Find the work-done (in J) by agency
maintaining the angular velocity of rod constant when the sleeve slips to a distance. r = r2. [Given r1

= 1m and r2 = 3m]

6) A small mass particle is projected with an initial velocity v0 tangent to the horizontal rim of a
smooth hemispherical bowl at a radius v0 from the vertical centre line as how n at point A. As the
particle slides past point B, a distance r from the vertical centre line and h depth blow its velocity v
makes an angle θ with the horizontal tangent to the bowl through B.

0 0

If . Find K. [Given v = m/s, h = 3m, r = 5m]

SECTION-I (iii)

1) In the figure shown are two blocks A and B of same mass connected with pulley and string to each
other. Initially both of them are at a height of h = 0.5 m from ground. After they are released they
move in either direction and one of them strike the ground. For, the interval from releasing to when
one of them strike, some physical quantities are in column I and their modulus values in SI units are
in column II.

Column I Column II
(A) Velocity of A immediately before any one of them strike ground. (P) 1
(B) Velocity of B immediately before any one of them strike ground. (Q) 2
(C) Ratio of work done by gravity on A to work done by gravity on B. (R) 3
(D) Acceleration of block A before any one of them strike ground. (S) 4
(T) 5
(A) A → Q;B → P;C → Q;D → S
(B) A → S;B → P;C → R;D → Q
(C) A → R;B → P;C → Q;D → S
(D) A → P;B → R;C → Q;D → S

2) A block of mass m lies on wedge of mass M. The wedge in turn lies on smooth horizontal surface.
Friction is absent everywhere. The wedge block system is released from rest. All situation given in
column–I are to be estimated in duration the block undergoes a vertical displacement 'h' starting
from rest (assume the block to be still on the wedge, g is acceleration due to gravity).

Column I Column II
(P) Work done by normal reaction acting on the block is (1) Positive
Work done by normal reaction (exerted by block) acting on
(Q) (2) Negative
wedge is
The sum of work done by normal reaction on block and work
(R) (3) Zero
done by normal reaction (exerted by block) on wedge is
(S) Net work done by all forces on block is (4) Less than mgh in magnitude
(A) P → 2;Q → 4;R → 1;S → 4
(B) P → 1;Q → 4;R → 2;S → 4
(C) P → 2;Q → 4;R → 1;S → 4
(D) P → 2;Q → 4;R → 1;S → 4

3) A particle of mass 1 kg is released from rest at point A as shown, a vertical distance h1 above the
ground. It slides down an inclined track, around a circular loop of radius R, then up another incline
that forms an angle of 45° with the horizontal. The block slides off the track at point C, which is at
height R above the ground. Assume the entire track to be frictionless. At point D normal contact
force is 22 N and velocity of the particle is m/s. Then :

List-I List-II

(P) h1 (1)

(Q) R (2)

(R) h2 (3)

(S) x0 (4)

(A) P → 2;Q → 3;R → 1;S → 4

(B) P → 3;Q → 2;R → 4;S → 1
(C) P → 4;Q → 1;R → 3;S → 2
(D) P → 1;Q → 4;R → 2;S → 3

PART 2 : CHEMISTRY

SECTION-I (i)

1)

For 1 mol of an ideal gas work in process AB will be :-

(A) 100R
(B) –100R
(C) 100 R [1 + ln2]
(D) 100R ln2

2) The figure represents the processes AB, BC and CA undertaken by a certain mass of an ideal gas.
Along the path AB, the gas is isothermally compressed with release of 800 J heat to the
surroundings. It is then compressed adiabatically along the path BC and the work done is 500 J. The
gas then returns to the state A along path CA and absorbs 100 J heat from the surroundings. The
work done by the gas along the path CA is

(A) –300 J
(B) –900 J
(C) –600 J
(D) –400 J

3) The enthalpy of tetramerization of X in gas phase (4X(g) → X4(g)) is – 100 kJ/mol at 300 K. The
enthalpy of vaporisation for liquid X and X4 are respectively 30 kJ/mol and 72 kJ/mol respectively. ΔS
for tetramerization of X in liquid phase is – 125 J / K mol at 300 K. What is the ΔG at 300 K for
tetramerization of X in liquid phase ?

(A) –52 kJ/mol

(B) –89.5 kJ/mol
(C) –14.5 kJ/mol
(D) None of these

4) An ideal gas (γ = 1.4) is used in a carnot cycle as a working substance. The efficiency of the cycle,
if as a result of an adiabatic expansion, the gas volume increases 2.75 times, is [(1.5)2.5 = 2.75]

(A)

(B)

(C) 50%
(D) 25%

SECTION-I (ii)

1) For which of the following reaction |ΔH| > |ΔU| :

(A)
at 1 bar and 127ºC
(B)
(C)
(D) at 1 bar and 27ºC

2) Two moles of an ideal gas (Cv, m R) The correct statement is/are

(A) The pressure at B is 2.0 bar

(B) The temperature at D is 450 K
(C) ΔHCD = 1000 R
(D) ΔUBC = 375 R

3) Which of the following statement is (are) correct?

For an exothermic reactions,

(A)

(B) is same as the of carbon (graphite)

(C) all exothermic reactions have a free energy change negative at any 'T'

(D) for a reaction , the heat at constant pressure and the heat at constant
volume at a given temperature are same.

SECTION-II

1) One mole ideal monoatomic gas is heated according to path AB and AC.
If temperature of state B and state C are equal.

2) 1 mole ideal monoatomic gas follows process , then molar heat capacity of gas in
Joules / K mole is (R = 8J/K mole)
3) 18gm of ice is converted into water at 0°C and 1 atm. The entropies of H2O(s) and H2O(l) are 38.2
and 60 J/mol K respectively. The enthalpy change for this coversion is (in kJ/mol)

4) A diatomic ideal gas is expanded isothermally to 32 times of it’s initial volume then it is cooled to
restore to initial entropy at constant volume. Calculate ratio of intial temperature to final
temperature

5) Use the following data to answer the questions below :

(in Kcal)

6) The enthalpy changes for the following processes are listed below :
Cl2(g) = 2Cl(g) , 242.3 kJ mol–1
I2(g) = 2I(g) , 151.0 kJ mol–1
ICl(g) = I(g) + Cl(g),211.3 kJ mol–1
I2(s) = I2(g), 62.7 kJ mol–1
Given that the standard states for iodine and chlorine are I2(s) and Cl2(g), the standard enthalpy of
formation for ICl(g) (in kJ) is :

SECTION-I (iii)

1) Match the transformations in List-I with appropriate option in List-II

List-I List-II

(I) CO2(s) → CO2(g) (P) phase transition

(II) CaCO3(s) → CaO(s) + CO2(g) (Q) allotropic change

(III) (R) ΔH is positive

(IV) P(white, solid) ® P(red,solid) (S) ΔS is positive

(T) ΔS is negative
(A) I → P;II → R;III → T;IV → R
(B) I → P;II → R;III → S;IV → T
(C) I → R;II → S;III → R;IV → S
(D) I → P;II → S;III → Q;IV → S

2) Match the thermodynamic processes given under Column-I with the expressions given under
Column-II.

Column - I Column - II

(A) Freezing of water at 273 K and 1 atm (P) q = 0

(B) Expansion of 1 mol of an ideal gas into a vacuum

(Q) w = 0
under isolated conditions

(C) Mixing of equal volumes of two ideal gases at

constant temperature and pressure in an isolated (R) ΔSsys < 0
container

(D) Reversible heating of H2(g) at 1 atm from 300 K to

600 K followed by reversible cooling to 300 K at 1 (S) ΔU = 0
atm followed by reversible cooling to 300 K at 1 atm

(T) ΔG = 0

(A) A → R,T;B → P,Q,S;C → P,Q,S;D → P,Q,S,T

(B) A → P,R;B → P,Q,R;C → P,Q,S;D → Q,R,S
(C) A → P,Q,;B → S,T;C → Q,T,S;D → P,T
(D) A → S,T;B → P,Q,S;C → P,Q,T;D → P,Q,R,T

3) U = Internal energy, S = Entropy, H = Enthalpy, G = Gibb's free energy, P = Pressure, V =

Volume, T = Temperature.

List-I List-II

(P) (1) P

(Q) (2) V

(R) (3) T

(S) (4) –S

(5) S
(A) P → 3;Q → 2;R → 5;S → 3
(B) P → 3;Q → 2;R → 4;S → 3
(C) P → 1;Q → 2;R → 4;S → 3
(D) P → 3;Q → 2;R → 4;S → 2

PART 3 : MATHEMATICS

SECTION-I (i)
1) A cat moves two steps forward or one step upward in a grid having milk at one corner as shown in
adjacent diagram. If cat starts from diagonally opposite corner then number of ways in which it can
reach to the milk is

11
(A) C6
8
(B) C6
8
(C) C3
8
(D) C3.2!.2!2!

2) Two variants of a test paper are distributed among 12 students. Number of ways of seating of the
students in two rows so that the students sitting side by side do not have identical papers & those
sitting in the same column have the same paper is:

(A)

(B)

(C)
(D)

3) If r, s, t are prime numbers and p, q are the positive integers such that their HCF is rs2t and their
LCM is r2s3t, then the numbers of ordered pair of (p, q) is -

(A) 4
(B) 18
(C) 36
(D) 72

4) Consider 4 boxes, where each box contains 3 red balls and 2 blue balls. Assume that all 20 balls
are distinct. In how many different ways can 10 balls be chosen from these 4 boxes so that from each
box at least one red ball and one blue ball are chosen ?

(A) 21816
(B) 85536
(C) 12096
(D) 156816

SECTION-I (ii)

1) A line divides a plane into 2 regions. Two lines divide the plane into maximum 4 regions. If Ln is
the maximum number of regions into which a plane can be divided by n lines then which of the
following is/are true :
(A) L20 = 211
(B) L10 = 56
(C) L15 = 121
(D) L25 = 326

2) The number of ways in which twenty identical icecream cones can be distributed among Ram,
Shyam and Ghanshyam such that none of them get more than eight icecream cones-

(A) 15
(B) 21
(C) Number of non negative integral solution of the equation x + y + z = 5
(D) sum of number of diagonals and number of sides in a polygon having six sides

3) Number of ways in which 15 indistinguishable oranges can be distributed in 3 different boxes so

that every box has atmost 8 oranges, are α then α is divisible by

(A) 26
(B) 52
(C) 10
(D) 5

SECTION-II

1) Let and A be a non-empty subset of T. is the sum of all elements of

set A. The number of all nonempty subsets A of T such that 3 divides but 5 does not divides
is ___

2) Consider seven digit number x1 x2 x3 ... x7 where x1, x2, ...., x7 0 having the property that x4 is the
greatest digit and all digits towards the left and right of x4 are in decreasing order. Then total
number of such numbers in which all digits are distinct is _______

3) Five persons shoot each other such that no one shoots himself, every one shoots exactly once and
no shot is wasted, then the number of ways in which exactly one person is not hit is k then the value
of k/10 is ,

4) The number of ways in which 5 X's can be placed in the squares of the figure so that no rows

remains empty is:

5) Let be an English alphabet & is serial number of α–(s(a) = 1, s(b) = 2...s(z) = 26). By
using all 7 letters of word "VICTORY" seven letter words are forming in dictionary order. If rank of "
" is 1000 then find =
(Where are the letters from the word "VICTORY")

6) All six digit numbers containing each of the digits 1, 2, 3, 4, 5, 6 exactly once, and not divisible by
5, are arranged in decreasing order. Then sum of two middle digits in 200th number in list is

SECTION-I (iii)

1)

LIST-I LIST-II

Number of ways of selecting two parallel lines from 12

(P) (1) 30
edges and 12 face diagonals of a cube is

(Q) Number of ways of selecting two skew face diagonals is (2) 24

Number of ways of selecting an edge and a face

(R) (3) 72
diagonal such that they are skew is

Number of ways of selecting two co-planar and

(S) perpendicular lines from 12 edges and 12 face diagonals (4) 54
of a cube is

(5) 52
(A) P → 2;Q → 3;R → 1;S → 4
(B) P → 2;Q → 1;R → 3;S → 4
(C) P → 1;Q → 2;R → 3;S → 5
(D) P → 5;Q → 1;R → 3;S → 1

2) A is set containing n-elements. P and Q are two subsets of set A.

Match each entry in List-I to the correct entry in List-II.

List-I List-II

If P ∩ Q = ϕ. Then number of such ordered pair

(P) (1) 2n
(P, Q) can be

If P ∪ Q = A. Then number of such ordered pair

(Q) (2) 3n
(P, Q) can be

(R) Number of such ordered pair (P, Q) can be (3) 4n

n(P) = n(Q). Then number of such ordered pair 2n

(S) (4) Cn
(P, Q) can be

(5) n.3n–1
The correct options is
(A) P → 2;Q → 5;R → 1;S → 4
(B) P → 2;Q → 2;R → 3;S → 4
(C) P → 3;Q → 2;R → 1;S → 2
(D) P → 3;Q → 5;R → 1;S → 4

3)

Consider all possible permutation of the letters of the word INDIANOIL. Now, match the following
lists and then choose the correct option from amongst the given codes.

List-I List-II

The number of permutations which contain the word

(P) (1) 28866
INDIA is

The number of permutations which contain the word

(Q) (2) 1374
OIL is

The number of permutations which contains neither

(R) (3) 1260
the word OIL nor the word INDIA is

The number of permutations which contains at least

(S) (4) 120
one of the words OIL and INDIA is
(A) P → 4;Q → 3;R → 1;S → 2
(B) P → 2;Q → 1;R → 4;S → 3
(C) P → 3;Q → 1;R → 4;S → 2
(D) P → 2;Q → 3;R → 4;S → 2
ANSWER KEYS

PART 1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. B C A B

SECTION-I (ii)

Q. 5 6 7
A. A,D C A,B

SECTION-II

Q. 8 9 10 11 12 13
A. 0.50 500.00 20.00 4.00 8.00 5.00

SECTION-I (iii)

Q. 14 15 16
A. A D B

PART 2 : CHEMISTRY

SECTION-I (i)

Q. 17 18 19 20
A. C C C A

SECTION-I (ii)

Q. 21 22 23
A. B,C,D A,B,C A,B,D

SECTION-II

Q. 24 25 26 27 28 29
A. 8.00 16.00 5.95 4.00 -84.00 16.70

SECTION-I (iii)

Q. 30 31 32
A. A A B

PART 3 : MATHEMATICS
SECTION-I (i)

Q. 33 34 35 36
A. C D A A

SECTION-I (ii)

Q. 37 38 39
A. A,B,C,D A,D A,B

SECTION-II

Q. 40 41 42 43 44 45
A. 70.00 720.00 42.00 98.00 34.00 10.00

SECTION-I (iii)

Q. 46 47 48
A. B B A
SOLUTIONS

PART 1 : PHYSICS

1)

Value of F at any angular position 'θ' is given by

, here r is given by

Also i.e.
For small angular displacement 'dθ' work done by this fore
dw = F R dθ cos(90 – α)
= –F R sin α dθ

∴ work done in moving bead from A to B

∴ Energy provided at point A must be equal to this work done.

∴
2)

3)
30 gy = 50 gx ⇒ 3y = 5x ... (1)
y2 = x2 + 1.6 x
16x2 = 1.6 x × 9
x = 0.9 m ⇒ y = 1.5 m

4)

Assertion-1 : displacement is zero

w.p = 0

f = mg sinα

s = ut + at2
= ut

5)

6) Distance travelled by = = Time

taken =
7) p = mv = v=

p=

F=

W=

W=

W=

8)
9)

kR2 – mgR = mv2

k = 500

10)

11)

at heighest point (C)

When ACB is not removed
by WET (D to C)

wg = Δk

mg (2R)=

After removing ACB

kR – mg = ma2

12)
w=8

13)

Angular momentum conservation about O' O axis

– mv0r0 = – mvcosθr

...(1)
WET
wall = Δk
wg = Δk

...(2)

...(3)
by solving eqn. 1, 2, 3 k = 5.

14)

yA = 2yB ⇒ vA = 2vB
A moves ↓ and
B moves ↑ as
Tension on B is more than A.

⇒
mg – T = maA
2T – mg = maB
aA = 2aB

15) for block, WN + Wg =

for wedge,

By C.O.M.E,
WN, block + WN, wedge = 0

16)

µ + mg =

22 + 1 × 10 =

R=

PART 2 : CHEMISTRY

17) T– 300 =
T = 300 + 5V – 200
T = 5V + 100
PV = RT

P = 5R

= – 5R [(20 – 40) + 20 ln ]
= 5R [20 + 20ln2]
= 100 R[1 + ln2]

18) For overall cycle : ΔU = 0

∴ q = –W
qAB + qBC + qCA = –[WAB + WBC + WCA]
–800 + 0 + 100 = –[800 + 500 + WCA]
WCA = –600 J

19)

∆G = ∆H − T∆S

Convert entropy change to

The reaction that do not represent the standard enthalpy of formation are.

because the standard enthalpy of formation is defined as the enthalpy change when one
mole of a substance is formed from its constituent elements in their standard stages.

20) γ = 1.4
Adiabatic expansion ;
TVγ–1 = constant

∴
T1 = Higher temperature (TH)
T2 = Lower temperature (TL)
Given ⇒ (V2 = 2.75 V1)

η=

21) (A)
–ve –ve + 0.5 × RT
(B)
+ve = +ve + 1 RT
(C)
ΔH = ΔU + ΔngRT
–ve = –ve –ve
(D)
ΔH = ΔU + ΔngRT
–ve = –ve –ve

22)
For process CD

TD = 450K

Also, ΔHCD = nCpΔT =

23) (A) For exothemic reaction

(C) In a reaction if

If

(D) ΔH = ΔU + ΔngRT
for given reaction
Δng = 0
So, ΔH = ΔV

24) Process AC = polytropic process (P = KV)

Molar Heat capacity cm = cv +R/2 = 2R
Process AB = Isobaric

25) Cm = ⇒2×8
= 16 J/K mole.
TV–2 = K = TVn–1 ⇒ n = 1

26)

Question Explanation:
The question asks us to calculate the enthalpy change (ΔH) for the conversion of ice (H2O(s))
to water (H2O(l)) at 0°C and 1 atm. We are given the entropies of ice and water, which allows
us to relate the entropy change to the enthalpy change at constant temperature.
Given Data:

A. Mass of ice = 18 g
B. Temperature (T) = 0°C = 273.15 K (We'll use 273 for simplicity)
C. Entropy of H2O(s) (Sice) = 38.2 J/mol K
D. Entropy of H2O(l) (Swater) = 60 J/mol K

Concept:
Relationship between entropy change (ΔS), enthalpy change (ΔH) and temperature (T) for a
reversible process at constant temperature:

Solution:
ΔS = ΔH / T
We can rearrange this to solve for ΔH:
ΔH = T × ΔS
Fist, we need to calculate the number of moles of ice. Then, we calculate the change in entropy and
finally, we calculate the enthalpy change.

Mathematical Calculation:

A. Mole of ice: Molar mas of H2O = 18 g/mol Number of moles (n) = mass / molar mass = 18g /
18 g/mol = 1 mol
B. Entropy change (ΔS): ΔS = Swater – Sice = 60 J/mol K – 38.2 J/mol K = 21.8 J/mol K
C. Enthalpy change (ΔH): ΔH = T × ΔS = 273 K × 21.8 J/mol K = 5951.4 J/mol
D. Concert to kJ/mol: ΔH = 5951.4 J/mol × (1 kJ / 1000 J) = 5.9514 kJ/mol

Final Answer:
The enthalpy change for the conversion of ice to water is approximately 5.95 kJ/mol.

27)

28)
–116.2 = |R.E| + 7(–28.6)
R.E. = – 84K cal/mole
29)

=16.70

30)

(A) CO2(s) → CO2(g), (p) phase transition, (r) ΔH is positive, (s) ΔS is positive
(B) CaCO3(s) → CaO(s) + CO2(g), (r) ΔH is positive, (s) ΔS is positive
(C) → Cl2(g), (s) DS is positive
(D) P(white, solid) → P(red,solid), (p) phase transition, (q) allotropic change, (t) ΔS is negative

31)

(A) During freezing of water at 273 K and 1 atm the entropy change of system is negative ΔSsys
< 0 and the free energy change is zero ΔG = 0
(B) During expansion of 1 mol of an ideal gas into a vacuum under isolated conditions no heat
exchanged q = 0 no work is exchanged w = 0. There is no change in the internal energy ΔU =
0.
(C) During mixing equal volume of two ideal gas at constant temperature and pressure in an
isolated container no heat exchanged q = 0 no work exchanged w = 0 no change in internal
energy is changed ΔU = 0.
(D) During reversible heating of H2(g) at 1 atm from 300 K to 600 K followed by reversible
cooling to 300 K at 1 atm no heat is exchanged q = 0 no work exchange w = 0. There is no
change in internal energy ΔU = 0 no change in Gibb's Energy ΔG = 0.

32) (P) dU = TdS – PdV

∴
(Q) dH = TdS + VdP

(R) dG = VdP – SdT

PART 3 : MATHEMATICS
33)

Number of horizontal moves = 3 (each of two steps)

Number of vertical moves = 5 (each of one step)
⇒ required number of ways = number of arrangements

of HHHVVVVV

34) = total number of required possible ways is

12
C6 × 6 ! × 6! × 2! = × 6 ! × 6 ! × 2! = 2 × 12!

35)

36)
Case-I : when exactly one box provides four balls (3R 1B or 2R 2B)
Number of ways in this case 5C4 (3C1 × 2C1)3 × 4
Case-II : when exactly two boxes provide three balls (2R 1B or 1R 2B) each
Number of ways in this case (5C3 – 1)2 (3C1 × 2C1)2 × 6
Required number of ways = 21816
Language ambiguity : If we consider at least one red ball and exactly one blue ball, then
required number of ways is 9504. None of the option is correct.

37) Clearly the number of regions is maximized when no two lines are parallel and no three
and concurrent. Easy to see that L1 = 2, L2 = 4 and L3 = 7. For the general case, we observe
that when we add the nth line, this new line is cut by the previous n – 1 lines in n – 1 points
and hence the new line is divided into n segments. Each of these segments divides a previous
region into 2 parts and hence the number of new regions
Lines dividing a plane
added when we introduce the nth line is n. Thus we have the recurrence relation
Hence .

...... ...

Adding, we get

Thus

L10 = 56

L15=121
L20 = 211
L25 = 326

38) Using inclusion & exclusion principle, the required number of ways

= 231 – {234 – 18} = 15

Aliter : By actual counting, number of ways

∴ Total ways = 15.

39) Required ways = (Total possible ways without restriction) – (ways when any box can ≥ 9
oranges) Total possible ways are
x + y + z = 15 ⇒ 15 + 3 – 1C3 – 1 = 17C2
Ways when any box can have 9 oranges
x + y + z = 15
either one of x, y, z can have more then 9 oranges.
x + y + z = 15 – 9 = 6 with x ≥ 0, y ≥ 0, z ≥ 0
Number of ways are 3C1 × 6 + 3 – 1C3 – 1 = 3C1 × 8C2
Required ways are = 17C2 – 3C1 × 8C2
= 52 Ans.

40) Let

Let and

For to be divisible by 3, should be divisible by 3.

Total no. of ways A can be selected such that is divisible by 3 is

Now
Hence

can be 15 in total 13 ways.

can be 30 in total 4 ways. is divisible by 15 in 17 ways.

41) No of selections of 7 digits out of digit

1, 2, 3, ..., 9 = 9C7
No of digits out of these 7 selected digits excluding the greatest digit = 6

These 6 digits can be divided in two groups each having 3 digits

But the three digits on one side can go other side

Required ways
= 720

42)
43) A B C
1 1 3
1 2 2
1 3 1
2 1 2
2 2 1
= 98

44) 1000 word in IROVTYC

45) 6 (_ _ _ _ _) = 4 × 4! = 96 ;
5 _ _ _ _ _ = 120 = 5!
Now 5 6 _ _ _ _ = 4!
Now 5 4 _ _ _ _ = 4!
like wise 200th place middle digits have sum 10.

46)

(P) Number of ways of selecting two parallel edges equal as there are 3 edges parallel
to every edge. And 6 pair of parallel face diagonals.
(Q) For every face diagonal there are 5 skew face diagonals

∴ Number of ways = = 30
(R) For every edge there are 6 skew face diagonals
⇒ total number of ways = 12 × 6 = 72

(S) There are edge-edge pairs and 6 face-diagonals-face-diagonal pairs and 24 face
diagonal-edge pairs = 54

47) (P)

48)

(P) The number of permutations which contain the word 'INDIA'

(INDIA), N, O, I, L
Number of ways = 5! = 120
(Q) The number of permutations which contain the word 'OIL'
(OIL), I, N, D, I, A, N
Number of ways = 7!/2!2! = 1260
(R) The number of permutations which contains neither word 'OIL' nor 'INDIA'
Total number of permutation of all letters (III NN D A O L) = 91/3!2! – 5! – 7!/2!2! +
3!
= 28866
(S) Required permutations = Total permutations – 28866

=
= 30240 – 28866
= 1374